Optimization of 12 chiral analytes with 8 polymeric surfactants

Simple item page
dc.contributor.authorBilliot, Eugene
dc.contributor.authorBilliot, Fereshteh
dc.contributor.authorWarner, Isiah
dc.date.accessioned2022-02-21T20:59:00Z
dc.date.available2022-02-21T20:59:00Z
dc.date.issued2008-10-01
dc.description.abstractThis manuscript discusses the results of studies that were performed to determine optimum capillary electrophoresis (CE) conditions for the enantiomeric resolution of twelve chiral analytes with eight amino acid based polymeric surfactants. The parameters that were optimized include pH, buffer type, and concentration of surfactant. The results indicated that the optimum conditions for enantiomeric separations with the amino acid based polymeric surfactants examined in this study using CE were analyte dependent, not surfactant dependent. In other words, the optimum conditions for a particular analyte were the same for all the amino acid based polymeric surfactants examined in this study. The results of these studies indicate that when using a large group of related amino acid based polymeric surfactants only a few surfactants need to be optimized for each analyte under study. These studies were limited to anionic surfactants that contain the amino acids glycine, L-alanine, L-valine, and L-leucine only. No inference can be necessarily drawn about surfactants containing other types of amino acids such as threonine and serine, which contain extra heteroatoms, or phenylalanine that has an aromatic moiety.en_US
dc.identifier.citationBilliot, E., Billiot, F. and Warner, I.M., 2008. Optimization of 12 chiral analytes with 8 polymeric surfactants. Journal of chromatographic science, 46(9), pp.757-763.en_US
dc.identifier.doihttps://doi.org/10.1093/chromsci/46.9.757
dc.identifier.urihttps://hdl.handle.net/1969.6/90166
dc.language.isoen_USen_US
dc.publisherOxford Academicen_US
dc.rightsAttribution-NonCommercial 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.subjectoptimizationen_US
dc.subjectpolymericen_US
dc.subjectsurfactantsen_US
dc.subjectchiral analytesen_US
dc.titleOptimization of 12 chiral analytes with 8 polymeric surfactantsen_US
dc.typeArticleen_US

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
Billot_Eugene_Chromatographic.pdf
Size:
304.3 KB
Format:
Adobe Portable Document Format
Description:
Article
Download

License bundle

Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.72 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

COS Faculty Works